NH2-MIL-68（In）的后合成修饰及其在诺氟沙星萃取中的研究

doi:10.19640/j.cnki.jtau.2025.01.007

Journal of Tianjin Agricultural University ›› 2025, Vol. 32 ›› Issue (1): 34-38.doi: 10.19640/j.cnki.jtau.2025.01.007

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Post-Synthetic modification of NH₂-MIL-68（In）and its application in the extraction of norfloxacin

Yang Linyan, Chen Zhengrong, Fu Leiming, Diao Qilin, Zhang Dongchao, Li Cun

Tianjin Key Laboratory of Agricultural Animal Breeding and Healthy Husbandry, College of Animal Science and Veterinary Medicine, Tianjin Agricultural University, Tianjin 300392, China

Received:2024-04-07 Published:2025-03-04

Abstract

Abstract: Metal-Organic Frameworks（MOFs）is a kind of porous crystal material synthesized by coordination bond between metal ions or clusters and organic linking groups. NH₂-MIL-68（In）, as a typical Metal-Organic Framework, shows great application potential in gas storage, separation, catalysis and optoelectronics due to its high specific surface area, adjustable pore size and functionality. The purpose of this study is to investigate the structural characteristics, synthesis methods and application of NH₂-MIL-68（In）in related fields. Through the application of various experimental methods, NH₂-MIL-68（In）was prepared by the solvothermal method, and then NH₂-MIL-68（In）-AA and NH₂-MIL-68（In）-CMC samples were prepared via the method of Post-Synthetic Modification. The structural properties and performance of the products were systematically studied. Research has found that NH₂-MIL-68（In）has significant advantages in the extraction of norfloxacin due to its high specific surface area and pore volume. After analysis of norfloxacin extraction at different pH values, NH₂-MIL-68（In）-CMC and NH₂-MIL-68（In）-AA had the best effects in norfloxacin extraction at pH=10. And NaOH was found to have the best elution effect. This study not only deepens the understanding of the structure and properties of NH₂-MIL-68（In）and its subsequent synthesized products, but also provides experimental basis for the further development of this material in practical applications.

Key words: NH₂-MIL-68（In）, MOFs, extraction, norfloxacin

CLC Number:

O658.2

Yang Linyan, Chen Zhengrong, Fu Leiming, Diao Qilin, Zhang Dongchao, Li Cun. Post-Synthetic modification of NH₂-MIL-68（In）and its application in the extraction of norfloxacin[J]. Journal of Tianjin Agricultural University, 2025, 32(1): 34-38.

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Post-Synthetic modification of NH₂-MIL-68（In）and its application in the extraction of norfloxacin

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Post-Synthetic modification of NH2-MIL-68（In）and its application in the extraction of norfloxacin

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Post-Synthetic modification of NH₂-MIL-68（In）and its application in the extraction of norfloxacin