沼气净化中脱硫技术的研究进展

天津农学院学报 ›› 2016, Vol. 23 ›› Issue (2): 57-59.

沼气净化中脱硫技术的研究进展

贾斌, 靳登超^通信作者, 鲍振博, 江薇, 杨帆, 汤玥, 胡文韬, 王海粟

天津农学院工程技术学院,天津 300384

出版日期:2016-06-20 发布日期:2019-10-14

Research Review of Biogas Desulfurization

JIA Bin, JIN Deng-chao^{Corresponding Author}, BAO Zhen-bo, JIANG Wei, YANG Fan, TANG Yue, HU Wen-tao, WANG Hai-su

College of Engineering and Technology, Tianjin Agricultural University, Tianjin 300384, China

Online:2016-06-20 Published:2019-10-14

摘要/Abstract

摘要： 沼气脱硫是沼气净化中面临的实际问题。本文从脱硫方法的原理出发,对比了各类脱硫工艺的优缺点,论述了各类脱硫技术的应用场合和发展前景。文中指出,生物脱硫技术因具有能耗低、无二次污染等优点而具有良好的发展前景。

关键词: 生物质能源, 沼气, 硫化氢, 脱硫技术

Abstract: Desulfurization is a practical problem in biogas purification. Based on the principle of desulfurization processes, the advantages and disadvantages of various desulfurization processes were compared, their engineering applications and development were also discussed in this paper. Depend on the study, it can be concluded that biological removal technology was a relativity better method both for its low energy consumption and no secondary pollution.

Key words: biomass energy, biogas, hydrogen sulfide, desulfurization

中图分类号:

X703.1

贾斌, 靳登超, 鲍振博, 江薇, 杨帆, 汤玥, 胡文韬, 王海粟. 沼气净化中脱硫技术的研究进展[J]. 天津农学院学报, 2016, 23(2): 57-59.

JIA Bin, JIN Deng-chao, BAO Zhen-bo, JIANG Wei, YANG Fan, TANG Yue, HU Wen-tao, WANG Hai-su. Research Review of Biogas Desulfurization[J]. Journal of Tianjin Agricultural University, 2016, 23(2): 57-59.

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链接本文: http://xuebao.tjau.edu.cn/CN/

http://xuebao.tjau.edu.cn/CN/Y2016/V23/I2/57

参考文献

[1] 李文哲,张波. 生物质能源现状与发展[J]. 现代农业,2006,328(11):1-5.
[2] 吴檬檬,于干,林春绵. 沼气脱硫技术研究进展[J]. 可再生能源,2012,30(10):73-78.
[3] 宋灿辉,肖波,史晓燕,等. 沼气净化技术现状[J]. 中国沼气,2007,25(4):23-27.
[4] Syed M A,Henshaw P F.Effect of tube size on performance of a fixed-film tubular bioreactor for consersion of hydrogen sulfide to elemental sulfur[J]. Water Research,2003,37(8):1932-1938.
[5] Miltner M,Makaruk A,Krischan J,et al.Chemical- oxidative scrubbing for the removal of hydrogensulphide from raw biogas:potentials and economics[J]. Water science and technology,2012,66(6):1354-1360.
[6] 姚磊. 生物处理水洗沼气中硫化氢所产生废水的研[D]. 苏州:苏州科技学院,2011.
[7] Monteleone G,DeFranceesco M,Galli S,et al. Deep H₂S removal from biogas for molten carbonate fuel cell(MCFC)systems[J]. Chemical Engineering Journal,2011,173(8):407-414.
[8] 李金洋,敖永华,刘庆玉. 沼气脱硫方法的研究[J]. 农机化研究,2008(8):228-230.
[9] 许宁,朱延美,冯文华. 脱除沼气中硫化氢的吸收剂改进[J]. 中国沼气,2004,22(1):35-37.
[10] 王钢,王欣,刘伟,等. 沼气脱硫技术研究[J]. 化学工程师,2008(1):33-44.
[11] 李坚,张书景,李兆辉. 污水处理厂消化沼气脱硫(硫化氢)实验[J]. 环境工程,2006,24(1):43-45.
[12] 陈沛全,曾彩明,李娴. 沼气净化脱硫工艺的研究进展[J]. 环境科学与管理,2010,35(4):125-129.
[13] Hernández S P, Chiappero M, Russo N,et al.A novel ZnO-based adsorbent for biogas purification in H₂ production systems[J]. Chemical Engineering Journal,2011,177(12):272-279.
[14] Osorio F,Torres J C.Biogas purification from anaerobic digestion in a waste water treatment plant for biofuel production[J]. Renewable Energy:An International Journal,2009,34(10):2164-2171.
[15] Hussain M,Abbas N,Fino D,et al.Novel mesoporous silica supported ZnO adsorbents for the desulphurization of biogas at low temperatures[J]. Chemical Engineering Journal,2012,188(4):222-232.
[16] Oyarzun,Arancibia P F,Canales C,et al. Bio-filtration of high concentration of hydrogen sulphide using Thio-bacillus thioparus[J]. Process Biochemistry,2003,39:165-170.
[17] Ramos I,Pérez R,Reinoso M,et al.Microaerobic digestion of sewage sludge on an industrial-pilot scale: The efficiency of biogas desulphurisation under different configurations and the impact of O₂ on the microbial communities[J]. Bioresource Technology,2014,164(7):338-346.
[18] Ramos I,Peña M,Fdz-Polanco M.Where does the removal of H₂S from biogas occur in microaerobic reactors[J] . Bioresource Technology,2014,166(8):151-157.
[19] Ramos I,Pérez R,Fdz-Polanco M.Microaerobic desulphurisation unit:A new biological system for the removal of H₂S from biogas[J]. Bioresource Technology,2013,142(8):633-640.
[20] Fernández M,Ramírez M,Pérez R M,et al.Hydrogen sulphide removal from biogas by an anoxic biotrickling filter packed with Pall rings[J]. Chemical Engineering Journal,2013,225(6):456-463.
[21] 胡明成,龙腾锐.沼气生物脱硫新技术[J].中国沼气,2006(2):15-19.
[22] Prescott M L,Harley P J,Klein A D.Microbiology[M]. New York:McGraw-Hill Companies,2003.
[23] Kim H, Kim J Y, Chung S J, et al.Long-term operation of a biofilter for simultaneous removal of H₂S and NH₃[J]. Air & Waste Management Association,2002,52(12):1389-1398.