AEO-7基取代酞菁钴催化氧化脱硫的动力学研究

doi:10.19640/j.cnki.jtau.2024.06.014

Journal of Tianjin Agricultural University ›› 2024, Vol. 31 ›› Issue (6): 85-89.doi: 10.19640/j.cnki.jtau.2024.06.014

• Researches and Scientific Notes • Previous Articles Next Articles

Kinetic study on the catalytic oxidation desulfurization of AEO-7 substituted cobalt phthalocyanine

Zhang Zimeng¹, Cong Fangdi^{1,Corresponding Author}, Zhang Chunlin¹, Yao Huiyu², Yang Wei¹, Chen Yingjun¹

1. College of Basic Sciences, Tianjin Agricultural University, Tianjin 300392, China;
2. Chemical Engineering Department, Juye County Vocational School, Juye 274900, Shandong Province, China

Received:2024-04-14 Online:2024-12-31 Published:2024-12-31

Abstract

Abstract: High quality fuel requires deep desulfurization in exquisite processes, mainly to remove the sulfur of thiophene compounds contained in the fuel. In order to explore catalysts for deep desulfurization of fuel, a one-pot synthesis method was used to prepare AEO-7 substituted cobalt phthalocyanine, which is amphiphilic to water and oil, for catalytic removal of sulfur from sodium sulfide and thiophene. And its catalytic desulfurization performance was compared with three water-soluble sulfonic acid amino substituted cobalt phthalocyanine desulfurization catalysts, based on the oxygen consumption kinetics of the reaction system. It was found that in the catalytic removal of sulfur from sodium sulfide solution, after 1 minute, the oxygen consumption of the AEO-7 substituted cobalt phthalocyanine catalytic reaction system was only 1/12 of the optimal water-soluble desulfurization catalyst. However, after 30 minutes of desulfurization of thiophene in isooctane, the oxygen consumption of AEO-7 substituted cobalt phthalocyanine catalytic system was about 10 times as high as that of water-soluble phthalocyanine catalytic systems. It can be seen that AEO-7 cobalt phthalocyanine has the potential to be applied in the deep desulfurization process of fuel.

Key words: synthesis, cobalt phthalocyanine, catalytic oxidation, desulfurization, thiophene

CLC Number:

O643.3

Zhang Zimeng, Cong Fangdi, Zhang Chunlin, Yao Huiyu, Yang Wei, Chen Yingjun. Kinetic study on the catalytic oxidation desulfurization of AEO-7 substituted cobalt phthalocyanine[J]. Journal of Tianjin Agricultural University, 2024, 31(6): 85-89.

Add to citation manager EndNote|Reference Manager|ProCite|BibTeX|RefWorks

URL: http://xuebao.tjau.edu.cn/EN/10.19640/j.cnki.jtau.2024.06.014

http://xuebao.tjau.edu.cn/EN/Y2024/V31/I6/85

References

[1] WANG F,XIAO K,SHI L,et al.Catalytic oxidative desulfurization of model fuel utilizing functionalized HMS catalysts:Characterization,catalytic activity and mechanistic studies[J]. Reaction Chemistry & Engineering,2021,6(2):289-296.
[2] JIANG L,MEI K,CHEN K,et al.Design and prediction for highly efficient SO₂ capture from flue gas by imidazolium ionic liquids[J]. Green Energy & Environment,2022,7(1):130-136.
[3] 王莉,卢莉莉,裴毅强. 植物油在柴油机上应用的研究现状分析[J]. 天津农学院学报,2016,23(3):61-65.
[4] MA H,ZHU Z,TANG P,et al.Hierarchical Ti-Beta zeolites with uniform intracrystalline mesopores hydrothermally synthesized via interzeolite transformation for oxidative desulfurization[J]. Microporous and Mesoporous Materials,2021,311:110702.
[5] 张士明,吴玉国,刘全杰,等. 燃油氧化脱硫研究进展[J]. 当代化工,2023,52(8):1996-2000.
[6] 薛科创,张文隆,成琳. 石墨烯基酞菁催化剂的制备及脱硫催化活性研究[J]. 化学工程师,2022,36(3):13-15.
[7] 逯贵广. 水溶性双核酞菁钴的合成及催化氧化性能研究[D]. 青岛:中国石油大学(华东),2010.
[8] 薛科创,马少华,孙宾宾. 四(4-羟基)苯基酞菁钴的合成及对去除噻吩的催化活性研究[J]. 化学工程师,2021,35(2):1-3.
[9] 丛方地,张立旺,王中立. 一种双亲酞菁钴催化脱硫的方法及应用:CN11644531A[P].2023-07-18.
[10] 桑立强,王晓东,黄培,等. 双核酞菁钴磺酸铵用于催化裂化汽油的脱臭[J]. 南京工业大学学报(自然科学版),2004,26(4):40-44.
[11] 蔡京荣,谢红飞. 以RTS为催化剂的湿法氧化脱硫技术[J]. 燃料与化工,2010,41(2):39-41.
[12] WANG M,FU S,PETKOV P,et al.Exceptionally high charge mobility in phthalocyanine-based poly(benzimid- azobenzophenanthroline)-ladder-type two- dimensional conjugated polymers[J]. Nature Materials,2023,22(7):880-887.
[13] YALAZAN H,KANTEKIN H,DURMUS M.Peripherally,non-peripherally and axially pyrazoline-fused phthalocyanines:Synthesis,aggregation behaviour,fluorescence,singlet oxygen generation,and photodegradation studies[J]. New Journal of Chemistry,2023,47(16):7849-7861.
[14] CONG F D,GAO G,LI J X,et al.Synthesis and aggregation study of optically active tetra-β-[(S)-2- octanyloxy]-substituted copper and nickel phthalocyanines[J]. Journal of Chemical Sciences,2010,122(6):813-818.
[15] 崔晓霞. PDS脱硫体系中双核磺化酞菁钴与硫化钠相互作用的研究[D]. 太原:太原理工大学,2019.
[16] CONG F D,WANG X Y,GAO G,et al.Facile synthesis of a water-soluble cobalt phthalocyanine derivative[J]. Asian Journal of Chemistry,2011,23(2):645-648.
[17] 宁浩宇,朱忠朋,郑伟平,等. 溶剂分子烃基结构对噻吩催化氧化的影响[J]. 石油炼制与化工,2023,54(11):41-46.
[18] 周宁,张月月,黄现礼,等. Pt/g-C₃N₄的可见光光催化异辛烷脱硫性能及机理[J]. 石油化工,2017,46(8):1012-1016.
[19] 赵文滔. 超声辅助非均相催化氧化脱硫脱硝实验研究[D]. 北京:华北电力大学,2022.
[20] 李艳丽,秦铭杉,韦冬微,等. UiO66的氨基化修饰及表征[J]. 天津农学院学报,2023,30(1):59-63.
[21] 张金龙. 钛硅分子筛的合成、改性与氧化脱硫过程研究[D]. 青岛:青岛科技大学,2014.

Kinetic study on the catalytic oxidation desulfurization of AEO-7 substituted cobalt phthalocyanine

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 8

Recommended Articles

Metrics

Comments

[1]	Wang Xin, Shi Xinyimei, Xie Fenlan, Fu Zhuang, Zhu Hualing, Ban Litong. Synthesis of the derivatives from 4-acylpyrazolone-5 and γ-aminobutyric acid and their effects on the dehydrogenase activity of Hypsizygus marmoreus mycelia [J]. Journal of Tianjin Agricultural University, 2022, 29(2): 1-6.
[2]	LIU Hong, MAO Xiang-shuang, LIU Huan, SHU Yue, HUANG Feng-ying, YANG Lin-yan. Studies on catalytic oxidation of VB₁by PEG modified Fe₃O₄ nanoparticles [J]. Journal of Tianjin Agricultural University, 2018, 25(4): 38-43.
[3]	ZHANG Li, LIU Jie, WU Qian, HE Pan-hua, ZHU Hua-ling, HUANG Zhi-qiang. Synthesis, Herbicidal and Antibacterial Activities, Quantum Chemical Calculation of New β-Diketone Derivatives Containing Glycylglycine Ester [J]. Journal of Tianjin Agricultural University, 2017, 24(1): 52-57.
[4]	JIA Bin, JIN Deng-chao, BAO Zhen-bo, JIANG Wei, YANG Fan, TANG Yue, HU Wen-tao, WANG Hai-su. Research Review of Biogas Desulfurization [J]. Journal of Tianjin Agricultural University, 2016, 23(2): 57-59.
[5]	LI Ping, XU Yan-ling, SHANG Zhi-qiang. Optimized Synthesis and Characterization of Epoxidized Linseed Oil Plasticizer [J]. Journal of Tianjin Agricultural University, 2016, 23(1): 38-42.
[6]	PANG Yue, ZHANG Shu-lin, BI Xiang-dong. Progress of Structure and Function of Photosynthetic Membrane Protein Complexes in Cyanobacteria [J]. Journal of Tianjin Agricultural University, 2013, 20(3): 45-51.
[7]	ZHU Hua-ling, BAN Li-tong, SHI Jun, BU Lu-xia, WEI Zhen. Reactivity Prediction of Benzoyl Acetone and Synthesis, Characterization, Antibacterial Activities of Its Metal Complexes [J]. Journal of Tianjin Agricultural University, 2012, 19(4): 18-23.
[8]	ZHANG Miao, Xv Wei, REN Jun-jie, ZHU Hua-ling, BAI Ya-nan, WANG Xue-rong. Synthesis, Characterization and Antibacterial Study of Some New 4-Amino Antipyrine Schiff Bases [J]. Journal of Tianjin Agricultural University, 2012, 19(1): 30-33.